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Beilstein J. Org. Chem. 2019, 15, 378–387, doi:10.3762/bjoc.15.34
Graphical Abstract
Figure 1: Selected examples of valuable β-ketosulfides. A: bioactive synthetic compounds, B: natural products....
Scheme 1: Different strategies for the preparation of β-ketosulfides.
Scheme 2: Thiol-free chemoenzymatic synthesis of β-ketosulfides.
Figure 2: Time-course plot for the CAL-B catalysed hydrolysis of 1a.
Scheme 3: One-pot two-step preparation of phenacylalkylsulfides. aReaction conditions: i. α-haloketone (0.25 ...
Scheme 4: Selective oxidation of the β-ketosulfide 2a.